133.5 Operator’s Guide for Anti-Icing

Tables

How to Use Liquid Anti-Icers

Equivalent Salt Spread Rates

Pure salt concentration and corresponding specific gravity (measured by a hydrometer) at 59º F

Gradation of salt specified by ASTM D 632 & MoDOT

Proportions for preparing sodium chloride solution from commercial grade salt (i.e., up to 5 percent impurities)

Light Snow Storm Weather Event

Light Snow with Period(s) of Moderate or Heavy Snow Weather Event

Moderate or Heavy Snow Storm Weather Event

Frost or Black Ice Weather Event

Freezing Rain Storm Weather Event

Sleet Storm Weather Event

Anti-icing is the snow and ice control practice of preventing the development of a bond between snow and/or ice and the pavement surface with the timely application of salt. Applying the right amount of salt at the right time will make snow removal operations more efficient and produce safer driving conditions during winter storms.

This article provides guidelines for the application of salt to the roadway for a variety of winter storm conditions. The timing and application rates were developed under the SHRP/FHWA Research Program, in which MoDOT participated. Many Maintenance personnel who have tested these procedures have found them to be valuable in their winter maintenance operations. The statewide implementation of this technology will help produce safer driving conditions on MoDOT’s continuous treatment routes during winter months.

133.5.1 Operations Guide for Maintenance Field Personnel

This is a guide to highway anti-icing operations for Maintenance field personnel. Its purpose is to recommend maintenance actions for preventing the formation or development of packed and bonded snow or bonded ice on the first priority continuous treatment routes during a variety of winter weather events. It is intended to complement the decision-making and management practices of a systematic anti-icing program so that continuous treatment routes can be efficiently maintained in the best possible condition.

These guidelines are based on the results of four years of anti-icing field testing conducted by 15 state DOTs, including MoDOT, and is supported by the Strategic Highway Research Program (SHRP) and the Federal Highway Administration (FHWA). Since then, it has been augmented with many additional years of anti-icing experience in different parts of our state.

Guidance for anti-icing operations during six winter weather events is available. The six events are:

• light snow storm
• light snow storm with period(s) of moderate or heavy snow
• moderate or heavy snow storm
• frost or black ice
• freezing rain storm
• sleet storm

The tables suggest the appropriate maintenance action to take during initial and follow-up anti-icing operations for a given precipitation or icing event. Each action is defined for a range of pavement temperatures and an associated temperature trend. For some events the operation is dependent not only on the pavement temperature and trend, but also upon the pavement surface or the traffic condition at the time of the action. Many of the maintenance actions involve the application of salt in either a dry solid, pre-wetted or brine (liquid) form. Pre-wetted solid and brine are the two primary forms on which we need to concentrate. Application rates are given for each form where appropriate. These are suggested rates and should be adjusted, if necessary, to achieve the effectiveness for local conditions.

Comments and notes are given in each table where appropriate to further guide field maintenance personnel for their anti-icing operations.

133.5.2 Glossary

Preparing for winter weather in Butler County

Black ice. Popular term for a very thin coating of clear, bubble-free, homogenous ice which forms on a pavement with a temperature at or slightly above 32º F when the temperature of the air in contact with the ground is below the freezing-point of water and small slightly supercooled water droplets deposit on the surface and coalesce (flow together) before freezing.

Brine. Water saturated with common salt (NaCl), also liquid salt or liquid chemical.

Continuous Treatment Routes. All National Highway System (NHS) routes, all remaining arterial (RA) routes, and all collector routes over 1700 AADT. These routes receive a continuous application of snow and ice control treatments over the entire length of the route.

Dew Point. The temperature that a vapor begins to condense.

Freezing rain. Super-cooled droplets of liquid precipitation falling on a surface whose temperature is below or slightly above freezing, resulting in a hard, slick, generally thick coating of ice commonly called glaze or clear ice. Non-super-cooled raindrops falling on a surface whose temperature is well below freezing will also result in glaze.

Frost. Also called hoarfrost. Ice crystals in the form of scales, needles, feathers or fans deposited on surfaces cooled by radiation or by other processes. The deposit may be composed of drops of dew frozen after deposition and of ice formed directly from water vapor at a temperature below 0º C (32º F) (sublimation).

Light Snow. Snow falling at the rate of less than 1/2 in. per hour; visibility is not affected adversely.

Moderate or heavy snow. Snow falling at a rate of 1/2 in. per hour or greater; visibility may be reduced.

Pre-treatment. This is the practice of applying salt brine at 44 gallons per lane mile to dry pavement prior to the winter event, or the application of pre-wetted salt to the surface prior to snow and ice bonding to the pavement.

Pre-wetting. Pre-wetting is the practice of applying salt brine to dry salt before it is placed on the pavement, and should be done at 10 to 15 gallons per ton. Liquid calcium chloride may be used for pre-wetting salt at temperatures below 15° F.

Sleet. A mixture of rain and of snow that has been partially melted by falling through an atmosphere with a temperature slightly above freezing.

Slush. Accumulation of snow that lies on an impervious base and is saturated with water in excess of its freely drained capacity. It will not support any weight when stepped or driven on but will "squish" until the base support is reached.

Spread Rate. The salt application rate in either the solid or liquid form. For solid applications it is simply the weight of the salt applied per lane mile. For liquid applications it is the volume (gallons) of brine applied per lane mile.

133.5.3 Tables

Table 133.5.3.1 How to Use Liquid Anti-Icers

Pounds of Ice Melted per Pound of Salt

Temperature, ° F	One Pound of Salt (sodium chloride)
30	46.3 lbs. of ice
25	14.4 lbs. of ice
20	8.6 lbs. of ice
15	6.3 lbs. of ice
10	4.9 lbs. of ice
5	4.1 lbs. of ice
0	3.7 lbs. of ice

Table 133.5.3.2 Equivalent Salt Spread Rates

Solid or Pre-wetted Solid (lbs./lane-mile)	Salt Brine, 23% Concentration NaCL (gallon/lane-mile)
25	11
50	22
75	33
100	44
125	55
150	65
200	87

Table 133.5.3.3 Pure salt concentration and corresponding specific gravity (measured by a hydrometer) at 59º F

Percent salt	Specific gravity at 59º F	Percent of saturation	Weight 1 of salt, lb/gal
0	1.000	0	0
5	1.035	20	0.43
6	1.043	24	0.52
7	1.050	28	0.61
8	1.057	32	0.71
9	1.065	36	0.80
10	1.072	40	0.90
11	1.080	44	0.99
12	1.087	48	1.00
13	1.095	52	1.10
14	1.103	56	1.29
15	1.111	60	1.39
16	1.118	63	1.49
17	1.126	67	1.60
18	1.134	71	1.71
19	1.142	75	1.81
20	1.150	79	1.92
21	1.158	83	2.03
22	1.166	87	2.14
23	1.175	91	2.26
24	1.183	95	2.37
25	1.191	99	2.45
25.2	1.200	100
1Note: Weight of commercial salt required = (weight of pure NaCl from table) ÷ (purity in percent)

Table 133.5.3.4 Gradation of salt specified by ASTM D 632 & MoDOT

Sieve size	Weight % passing
	ASTM Gr. 1	ASTM Gr. 2	MoDOT
3/4 in.	-	100	-
1/2 in.	100	-	100
3/8 in.	95-100	-	95-100
No. 4	20-90	29-100	15-95
No. 8	10-60	10-60	5-65
No. 30	0-15	0-15	0-15
Note: ASTM Gr. 1 is the most commonly used gradation in the U.S.

Table 133.5.3.5 Proportions for preparing sodium chloride solution from commercial grade salt (i.e., up to 5 percent impurities)

Actual %NaCl	Weight NaCl		Crystalization temperature, º F	Weight per unit volume of solution, lb/gal
	per volume solution, lb/gal	per volume water, lb/gal
10	0.9	0.8	20	8.95
15	1.4	1.3	12	9.28
20	1.9	1.7	0	9.6
231	2.3	1.9	-6	9.76
25	2.5	2.1	-16	10.3
1 Note: This is the approximate eutectic composition, i.e., the composition that results in the lowest temperature at which a solution can exist while remaining completely liquid.

133.5.3.6 Tables for First Priority Continuous Treatment Routes

Table 133.5.3.6.1 Light Snow Storm Weather Event

First Priority Continuous Treatment Routes

Pavement Temperature Range and Trend	Initial Operation				Subsequent Operations			Comments
	Pavement surface at time of initial operation	Maintenance action	Salt spread rates		Maintenance action	Salt spread rates
			Pre-wetted solid salt (lb/lane-mail)	Brine (gal/lane-mile)		Pre-wetted solid salt (lb/lane-mile)	Brine (gal/lane-mile)
Above 32º F, steady or rising	Dry, wet, slush or light snow cover	None, see comments	-	-	None, see comments	-	-	1) Monitor pavement temperature closely for drops toward 32º F and below, 2) Treat icy patches if needed with pre-wetted solid salt at 100 lb/lane-mile; plow if needed
Above 32º F, 32º F or below is imminent; ALSO 15 to 32º F, remaining in range	Dry	Apply brine or pre-wetted solid salt	100	44	Plow as needed, reapply liquid or solid chemical when needed	100	44	1) Applications will need to be more frequent at lower temperatures and higher snowfall rates , 2) It is not advisable to apply a straight brine at the indicated spread rate when the pavement temperature drops below 20º F , 3) Do not apply brine onto heavy snow accumulation or packed snow
	Wet, slush or light snow cover	Apply liquid or solid salt	100	44
0 to 15º F, remaining in range	Dry, wet, slush or light snow cover	Apply pre-wetted solid chemical	200	-	Plow as needed; reapply pre-wetted solid chemical when needed	200	-	1) Abrasives may be added to the salt to enhance traction at colder temperatures , 2) Liquid calcium chloride may be used for pre-wetting solid salt at colder temperatures
Below 0º F, steady or falling	Dry or light snow cover	Plow as needed	-	-	Plow and apply salt/abrasive mix as needed	-	-	1) If pavement becomes slick apply salt/abrasive mix to enhance traction. Salt will have limited melting power in this temperature range, 2) Pre-wet salt/abrasive mix with liquid calcium chloride.
Salt Applications. (1) Time initial and subsequent chemical applications to prevent deteriorating conditions or development of packed and bonded snow. (2) Apply salt ahead of traffic rush periods occurring during storm.
Plowing. If needed, plow before salt applications so that excess snow, slush, or ice is removed and pavement is wet, slushy, or lightly snow covered when treated.

Table 133.5.3.6.2 Light Snow with Period(s) of Moderate or Heavy Snow Weather Event

First Priority Continuous Treatment Routes

Pavement Temperature Range and Trend	Initial Operation				Subsequent Operations					Comments
	Pavement surface at time of initial operation	Maintenance action	Salt spread rates		Maintenance action	Salt spread rates
			Pre-wetted solid salt (lb/lane-mail)	Brine (gal/lane-mile)		Pre-wetted solid salt (lb/lane-mile)		Brine (gal/lane-mile)
						Light snow	Heavier snow	Light snow	Heavier snow
Above 32º F, steady or rising	Dry, wet, slush or light snow cover	None, see comments	-	-	None, see comments	-	-	-	-	1) Monitor pavement temperature closely for drops toward 32º F and below, 2) Treat slick patches if needed with pre-wetted solid salt at 100 lb/lane-mile or brine 44 gal/lane-mile; plow if needed
Above 32º F, 32º F or below is imminent; ALSO 20 to 32º F, remaining in range	Dry	Apply brine or pre-wetted salt	100	44	Plow as needed, reapply brine or pre-wetted solid salt when needed	100	200	44	88	1) Applications will need to be more frequent at lower temperatures and higher snowfall rates , 2) Do not apply brine onto heavy snow accumulation or packed snow, 3) After heavy snow periods and during light snowfall, reduce salt rate to 100 lb./lane-mile or 44 gal./lane-mile brine; continue to plow and apply salt as needed
	Wet, slush, or light snow cover	Apply brine or pre-wetted salt	100	44
10 to 32º F, remaining in range	Dry, wet, slush or light snow cover	Apply pre-wetted salt	200	-	Plow as needed, reapply pre-wetted solid salt when needed	200	250	-	-	1) Reduce salt rate to 200 lb./lane-mile after heavier snow periods and during light snowfall; continue to plow and apply salt as needed, 2) Liquid calcium chloride may be used for pre-wetted salt at colder temperatures
Below 10º F, steady or falling	Dry or light snow cover	Plow as needed	-	-	Plow and apply salt/abrasive mix as needed	-	-	-	-	As pavement becomes slick, apply salt/abrasive mix to enhance traction. Salt will have limited melting power at these temperatures.
Salt Applications. (1) Time initial and subsequent chemical applications to prevent deteriorating conditions or development of packed and bonded snow. (2) Anticipate increases in snowfall intensity. Apply higher rate treatments prior to or at the beginning of heavier snowfall periods to prevent development of packed and bonded snow. (3) Apply salt ahead of traffic rush periods occurring during storm.
Plowing. If needed, plow before salt applications so that excess snow, slush, or ice is removed and pavement is wet, slushy, or lightly snow covered when treated.

Table 133.5.3.6.3 Moderate or Heavy Snow Storm Weather Event

First Priority Continuous Treatment Routes

Pavement Temperature Range and Trend	Initial Operation				Subsequent Operations			Comments
	Pavement surface at time of initial operation	Maintenance action	Salt spread rates		Maintenance action	Salt spread rates
			Pre-wetted solid salt (lb/lane-mail)	Brine (gal/lane-mile)		Pre-wetted solid salt (lb/lane-mile)	Brine (gal/lane-mile)
Above 32º F, steady or rising	Dry, wet, slush or light snow cover	None, see comments	-	-	None, see comments	-	-	1) Monitor pavement temperature closely for drops toward 32º F and below, 2) Treat slick patches if needed with pre-wetted solid salt at 100 lb/lane-mile or with brine at 44 gal/lane-mile; plow if needed
Above 32º F, 32º F or below is imminent; ALSO 30 to 32º F, remaining in range	Dry	Apply brine or pre-wetted solid salt	100	44	Plow accumulation and reapply brine or solid salt as needed	100	44	1) If the desired plowing/treatment frequency cannot be maintained, the spread rate can be increased to 200 lb/lane-mile to accommodate longer operational cycles , 2) Do not apply brine onto heavy snow accumulation or packed snow
	Wet, slush or light snow cover	Apply brine or pre-wetted solid salt	100	44
20 to 30º F, remaining in range	Dry	Apply brine or pre-wetted solid salt	150-200	65-87	Plow accumulation and reapply brine or solid salt as needed	200	87	1) If the desired plowing/treatment frequency cannot be maintained, the spread rate can be increased to 400 lb/lane-mile to accommodate longer operational cycles , 2) Do not apply brine onto heavy snow accumulation or packed snow
	Wet, slush or light snow cover	Apply brine or pre-wetted solid salt	150-200	65-87
10 to 20º F, remaining in range	Dry, wet, slush or light snow cover	Apply pre-wetted solid salt	200	-	Plow accumulation and reapply brine or solid salt as needed	250	-	1) If the desired plowing/treatment frequency cannot be maintained, the spread rate can be increased to 500 lb/lane-mile to accommodate longer operational cycles , 2) Liquid calcium chloride may be used for pre-wetting salt at colder temperatures
Below 10º F, steady or falling	Dry or light snow cover	Plow as needed	-	-	Plow accumulation as needed	250	-	1) As pavement becomes slick, apply salt/abrasive mix to enhance traction. Salt will have limited melting power in this temperature range.
Salt Applications. (1) Time initial and subsequent chemical applications to prevent deteriorating conditions or development of packed and bonded snow – timing and frequency of applications will be determined primarily by plowing requirements. (2) Apply salt ahead of traffic rush periods occurring during storm.
Plowing. Plow before chemical applications so that excess snow, slush, or ice is removed and pavement is wet, slushy, or lightly snow covered when treated.

Table 133.5.3.6.4 Frost or Black Ice Weather Event

First Priority Continuous Treatment Routes

Pavement Temperature Range and Trend	Traffic Condition	Initial Operation			Subsequent Operations			Comments
		Maintenance action	Salt spread rates		Maintenance action	Salt spread rates
			Pre-wetted solid salt (lb/lane-mail)	Brine (gal/lane-mile)		Pre-wetted solid salt (lb/lane-mile)	Brine (gal/lane-mile)
Above 32º F, steady or rising	Any level	None, see comments	-	-	None, see comments	-	-	1) Monitor pavement temperature closely; begin treatment if it starts to fall to 32º F and below and is at or below dew point.
28 to 32º F, remaining in range or falling to 32º F or below and equal to or below dew point	Traffic rate less than 100 vehicles per hr	Apply brine or pre-wetted solid salt	25-65	11-28	Reapply pre-wetted solid salt as needed	25-65	-	1) Monitor pavement temperature closely; if pavement becomes wet or if thin ice forms, reapply salt at higher indicated rated, 2) Do not apply brine on ice so thickly that the pavement cannot be seen
	Traffic rate greater than 100 vehicles per hr	Apply brine or pre-wetted solid salt	25-65	11-28	Reapply brine pre-wetted solid salt as needed	25-65	11- 28
20 to 28º F, remaining in range and equal to or below dew point	Any level	Apply brine or pre-wetted solid salt	65-130	28-57	Reapply brine pre-wetted solid salt as needed	65 - 130	28 - 57	1) Monitor pavement temperature closely; if thin ice forms, reapply salt at higher indicated rated, 2) Applications will need to be more frequent at higher levels of condensation; if traffic volumes are not enough to disperse condensation, it may be necessary to increase frequency, 3) It is not advisable to apply a brine at the indicated spread rate when the pavement temperature drops below 20º F.
10 to 20º F, remaining in range and equal to or below dew point	Any level	Apply pre-wetted solid salt	130 - 200	-	Reapply pre-wetted solid salt as needed	130 - 200	-	1) Monitor pavement temperature closely; if thin ice forms, reapply salt at higher indicated rated, 2) Applications will need to be more frequent at higher levels of condensation; if traffic volumes are not enough to disperse condensation, it may be necessary to increase frequency,
Below 10º F, steady or falling	Any level	Apply abrasives	-	-	Apply abrasives as needed	-	-	1) Monitor pavement closely, salt will have limited melting power in this temperature range, 2) Liquid calcium chloride may be used for pre-wetting salt/abrasive mix at colder temperatures.
Timing. (1) Conduct initial operation in advance of freezing. Apply brine up to 3 hr in advance. Use longer advance times in this range to effect drying when traffic volume is low. Apply pre-wetted solid salt 1 to 2 hr in advance. (2) In the absence of precipitation, brine at 33 gal/lane-mile has been successful in preventing bridge deck icing when placed up to 4 days before freezing on higher volume roads and 7 days before on lower volume roads.

Table 133.5.3.6.5 Freezing Rain Storm Weather Event

First Priority Continuous Treatment Routes

Pavement Temperature Range and Trend	Initial Operation		Subsequent Operations		Comments
	Maintenance action	Salt spread rate (lb/lane-mile)	Maintenance action	Salt spread rates (lb/lane-mile)
Above 32º F, steady or rising	None, see comments	-	None, see comments	-	1) Monitor pavement temperature closely for drops toward 32º F and below, 2) Treat icy patches if needed with pre-wetted solid chemical at 75 – 100 lb/lane-mile.
Above 32º F, 32º F or below is imminent	Apply pre-wetted solid chemical	75-100	Reapply pre-wetted solid chemical as needed	75-100	Monitor pavement temperature and precipitation closely;
20 to 32º F, remaining in range	Apply pre-wetted solid chemical	75-250	Reapply pre-wetted solid chemcial as needed	75 - 250	1) Monitor pavement temperature and precipitation closely, 2) Increase spread rate toward higher indicated rate with decrease in pavement temperature or increase in intensity of freezing rainfall, 3) Decrease spread rate toward lower indicated rate with increase in pavement temperature or decrease in intensity of freezing rainfall.
10 to 20º F, remaining in range	Apply pre-wetted solid chemical	250 - 400	Reapply pre-wetted chemical as needed	250 - 400	1) Monitor pavement temperature and precipitation closely, 2) Increase spread rate toward higher indicated rate with increase in intensity of freezing rainfall, 3) Decrease spread rate toward lower indicated rate with decrease in intensity of freezing rainfall.
Below 10º F, steady or falling	Apply abrasives	-	Apply abrasives as needed	-	It is not recommended that chemicals be applied in this temperature range
Salt Applications. (1) Time initial and subsequent chemical applications to prevent glaze ice conditions. (2) Apply chemical ahead of traffic rush periods occurring during storm.

Table 133.5.3.6.6 Sleet Storm Weather Event

First Priority Continuous Treatment Routes

Pavement Temperature Range and Trend	Initial Operation		Subsequent Operations		Comments
	Maintenance action	Dry chemical spread rate (lb/lane-mile)	Maintenance action	Salt spread rate (lb/lane-mile)
Above 32º F, steady or rising	None, see comments	-	None, see comments	-	1) Monitor pavement temperature closely for drops toward 32º F and below, 2) Treat icy patches if needed with pre-wetted solid chemical at 125 lb/lane-mile.
Above 32º F, 32º F or below is imminent	Apply pre-wetted solid chemical	125	Reapply pre-wetted solid chemical as needed	125	Monitor pavement temperature and precipitation closely;
28 to 32º F, remaining in range	Apply pre-wetted solid chemical	125-325	Reapply pre-wetted solid chemcial as needed	125 - 325	1) Monitor pavement temperature and precipitation closely, 2) Increase spread rate toward higher indicated rate with increase in sleet intensity, 3) Decrease spread rate toward lower indicated rate with decrease in sleet intensity.
10 to 28º F, remaining in range	Apply pre-wetted solid chemical	250 - 400	Reapply pre-wetted chemical as needed	250 - 400	1) Monitor pavement temperature and precipitation closely, 2) Increase spread rate toward higher indicated rate with increase in sleet intensity, 3) Decrease spread rate toward lower indicated rate with decrease in sleet intensity.
Below 10º F, steady or falling	Plow as needed	-	Apply abrasives as needed	-	1) It is not recommended that chemicals be applied in this temperature range, 2) Abrasives can be applied to enhance traction.
Salt Applications. (1) Time initial and subsequent salt applications to prevent the sleet from bonding to the pavement. (2) Apply salt ahead of traffic rush periods occurring during storm.